Matches in SemOpenAlex for { <https://semopenalex.org/work/W2589779862> ?p ?o ?g. }
Showing items 1 to 78 of
78
with 100 items per page.
- W2589779862 endingPage "930" @default.
- W2589779862 startingPage "925" @default.
- W2589779862 abstract "The effects of ‘through-conjugation’ (TC) vs. ‘cross-conjugation’ (CC) have been studied in a series of [n]dendralene analogues with the aid of high-level molecular orbital (MO) calculations using composite G3MP2 method. The energy differences between TC and the corresponding CC alkenes have been determined and found to be small and comparable to the conformational barrier for rotation around the C–C single bond. The destabilisation in CC vs. TC alkenes per C = C unit does not show different trends within the even and odd series of [n]dendralenes. The observed differences in UV–vis and nuclear magnetic resonance (NMR) spectra and chemical reactivities between even and odd [n]dendralenes are thus solely due to conformational preferences which of course affect C = C bond conjugation (π-delocalisation). We also propose new partially hydrogenated graphene materials (‘dendraphenes’) which were introduced in the isodesmic reactions designed to study CC." @default.
- W2589779862 created "2017-03-03" @default.
- W2589779862 creator A5064679615 @default.
- W2589779862 date "2017-02-20" @default.
- W2589779862 modified "2023-10-14" @default.
- W2589779862 title "Quantification of cross-conjugation" @default.
- W2589779862 cites W1894187880 @default.
- W2589779862 cites W2041274650 @default.
- W2589779862 cites W2077057919 @default.
- W2589779862 cites W2160850020 @default.
- W2589779862 cites W2236298509 @default.
- W2589779862 cites W2317411269 @default.
- W2589779862 cites W2484816978 @default.
- W2589779862 cites W2485175605 @default.
- W2589779862 cites W2519913361 @default.
- W2589779862 cites W2791641970 @default.
- W2589779862 cites W2963210970 @default.
- W2589779862 doi "https://doi.org/10.1080/00268976.2017.1292014" @default.
- W2589779862 hasPublicationYear "2017" @default.
- W2589779862 type Work @default.
- W2589779862 sameAs 2589779862 @default.
- W2589779862 citedByCount "2" @default.
- W2589779862 countsByYear W25897798622018 @default.
- W2589779862 countsByYear W25897798622023 @default.
- W2589779862 crossrefType "journal-article" @default.
- W2589779862 hasAuthorship W2589779862A5064679615 @default.
- W2589779862 hasConcept C121332964 @default.
- W2589779862 hasConcept C139210041 @default.
- W2589779862 hasConcept C139358910 @default.
- W2589779862 hasConcept C144557053 @default.
- W2589779862 hasConcept C147597530 @default.
- W2589779862 hasConcept C152365726 @default.
- W2589779862 hasConcept C15744967 @default.
- W2589779862 hasConcept C178790620 @default.
- W2589779862 hasConcept C184779094 @default.
- W2589779862 hasConcept C185592680 @default.
- W2589779862 hasConcept C2775884256 @default.
- W2589779862 hasConcept C32909587 @default.
- W2589779862 hasConcept C68381374 @default.
- W2589779862 hasConcept C77805123 @default.
- W2589779862 hasConcept C8010536 @default.
- W2589779862 hasConceptScore W2589779862C121332964 @default.
- W2589779862 hasConceptScore W2589779862C139210041 @default.
- W2589779862 hasConceptScore W2589779862C139358910 @default.
- W2589779862 hasConceptScore W2589779862C144557053 @default.
- W2589779862 hasConceptScore W2589779862C147597530 @default.
- W2589779862 hasConceptScore W2589779862C152365726 @default.
- W2589779862 hasConceptScore W2589779862C15744967 @default.
- W2589779862 hasConceptScore W2589779862C178790620 @default.
- W2589779862 hasConceptScore W2589779862C184779094 @default.
- W2589779862 hasConceptScore W2589779862C185592680 @default.
- W2589779862 hasConceptScore W2589779862C2775884256 @default.
- W2589779862 hasConceptScore W2589779862C32909587 @default.
- W2589779862 hasConceptScore W2589779862C68381374 @default.
- W2589779862 hasConceptScore W2589779862C77805123 @default.
- W2589779862 hasConceptScore W2589779862C8010536 @default.
- W2589779862 hasFunder F4320320961 @default.
- W2589779862 hasIssue "8" @default.
- W2589779862 hasLocation W25897798621 @default.
- W2589779862 hasOpenAccess W2589779862 @default.
- W2589779862 hasPrimaryLocation W25897798621 @default.
- W2589779862 hasRelatedWork W1993948678 @default.
- W2589779862 hasRelatedWork W2003256366 @default.
- W2589779862 hasRelatedWork W2007380041 @default.
- W2589779862 hasRelatedWork W2071073691 @default.
- W2589779862 hasRelatedWork W2083597126 @default.
- W2589779862 hasRelatedWork W2086473867 @default.
- W2589779862 hasRelatedWork W2089113400 @default.
- W2589779862 hasRelatedWork W2107040271 @default.
- W2589779862 hasRelatedWork W2133564150 @default.
- W2589779862 hasRelatedWork W2177849522 @default.
- W2589779862 hasVolume "115" @default.
- W2589779862 isParatext "false" @default.
- W2589779862 isRetracted "false" @default.
- W2589779862 magId "2589779862" @default.
- W2589779862 workType "article" @default.