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- W2590267648 abstract "Abstract Visible light response and superior dispersed S 6+ -doped TiO 2 nanoparticle catalysts (S-TiO 2 ) were prepared via ionic liquid of 1-butyl-3-methylimidazolium hexafluorophosphate. The phenol was used for the evaluation of the S-TiO 2 photocatalytic activity. S-TiO 2 was characterized by XPS, UV–vis DRS, FE-SEM, TEM, XRD, TG/DSC, FTIR, and BET. The results showed that S-TiO 2 with appropriate S doping prepared via ionic liquid had smaller particle size, better dispersion, higher activity, and higher surface area ( S BET ) than that prepared in water. Cationic S 6+ incorporation into TiO 2 lattice substitutes for Ti 4+ lattice site, generates Ti–O–S bonds in TiO 2 , and leads to the formation of donor defect levels in band gap, so that the photocatalytic sensitization of TiO 2 has been extended to visible light region. The optimal content in S doping for the better photocatalytic performance can optimize electrical properties of the intrinsic n -type TiO 2 by adding the adequate amount of donor defect of S Ti 2+ for considering the lifetime of the photo-induced charge pairs." @default.
- W2590267648 created "2017-03-03" @default.
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- W2590267648 date "2017-04-01" @default.
- W2590267648 modified "2023-10-18" @default.
- W2590267648 title "Visible light response and superior dispersed S-doped TiO 2 nanoparticles synthesized via ionic liquid" @default.
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- W2590267648 doi "https://doi.org/10.1016/j.apt.2017.02.007" @default.
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