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- W2590463947 abstract "Abstract The reaction of square planar complex [Ni(L2)]Cl2·2H2O (L2 = 3,14-diethyl-2,6,13,17-tetraazatricyclo[14,4,01.18,07.12]docosane) with ligands KNCS and H2cpdc generates 1D hydrogen-bonded infinite chains [Ni(L2)(NCS)2] (1) and [Ni(L2)(H-cpdc)2] (2) (H2cpdc = cyclopropanedicarboxylic acid). These compounds have been characterized by X-ray crystallography, spectroscopic, cyclic voltammetry and thermogravimetry. The crystal structures of compounds 1 and 2 show that each nickel(II) centre has an elongated distorted octahedral geometry with the axial ligands. Electronic spectra and redox potentials of the complexes 1 and 2 exhibit a high-spin octahedral environment, which is reflected by the nature of the axial ligands. The TGA behaviors of two compounds 1 and 2 are also significantly affected by the nature of the axial ligands." @default.
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- W2590463947 date "2017-05-01" @default.
- W2590463947 modified "2023-10-16" @default.
- W2590463947 title "1D hydrogen-bonded infinite chains from tetraaza macrocycle nickel(II) complexes and ligands" @default.
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- W2590463947 doi "https://doi.org/10.1016/j.poly.2017.02.024" @default.
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