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• W2590483839 abstract "Inspired by the homogeneous catalyst tris(pentafluorophenyl) borane [B(C6F5)3], which acts as a promotor of Si–H bond activation, we developed and studied a method of modifying silicon oxide surfaces using hydrosilanes with B(C6F5)3 as the catalyst. This dedihydrosiloxanation reaction yields complete surface coverage within 10 min at room temperature. Organic monolayers derived from hydrosilanes with varying carbon chain lengths (C8–C18) were prepared on oxidized Si(111) surfaces, and the thermal and hydrolytic stabilities of the obtained monolayers were investigated in acidic (pH 3) medium, basic (pH 11) medium, phosphate-buffered saline (PBS), and deionized water (neutral conditions) for up to 30 days. DFT calculations were carried out to gain insight into the mechanism, and the computational results support a mechanism involving silane activation with B(C6F5)3. This catalyzed reaction path proceeds through a low-barrier-height transition state compared to the noncatalyzed reaction path." @default.
• W2590483839 created "2017-03-03" @default.
• W2590483839 creator A5031382694 @default.
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• W2590483839 date "2017-02-23" @default.
• W2590483839 modified "2023-10-11" @default.
• W2590483839 title "Organic Monolayers by B(C₆F₅)₃-Catalyzed Siloxanation of Oxidized Silicon Surfaces" @default.
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• W2590483839 doi "https://doi.org/10.1021/acs.langmuir.7b00110" @default.
• W2590483839 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5343549" @default.
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