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• W2590823423 abstract "The chelation-controlled arylation reaction of chiral, enantiopure acyclic α-amino aldehydes enabled by a B/Zn exchange reaction between arylboronic acids and Et2Zn is reported. The presence of dibenzyl substituents at the nitrogen plays a key role in the stereochemical outcome of the reaction, and chelation is favored over the natural tendency of this type of substrate to undergo Felkin-Anh controlled additions with organomagnesium and organolithium reagents." @default.
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• W2590823423 date "2017-03-03" @default.
• W2590823423 modified "2023-09-24" @default.
• W2590823423 title "Stereoselective Arylation of Amino Aldehydes: Overriding Natural Substrate Control through Chelation" @default.
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• W2590823423 doi "https://doi.org/10.1021/acs.joc.7b00215" @default.
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