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- W2590881566 abstract "The metal-organic framework (MOFs) of MIL-53 was functionalized by aminosilane grafting and then incorporated into Ultem®1000 polymer matrix to fabricate mixed matrix hollow fiber membrane (MMHFM) with high separation performance. SEM, XRD, and TGA were performed to characterize the functionalized MIL-53 and prepared MMHFM. The filler particles were embedded in membrane successfully and dispersed well in the polymer matrix. The incorporation of MOFs endowed MMHFM better thermal stability. Moreover, effects of solvent ratio in spinning dope, spinning condition, and testing temperature on gas separation performance of MMHFM were investigated. By optimizing dope composition, air gap distance, and bore fluid composition, MMHFM containing functionalized MIL-53 achieved excellent gas permeance and CO 2 /N 2 selectivity. The CO 2 permeance increased from 12.2 GPU for pure Ultem HFM to 30.9 GPU and the ideal CO 2 /N 2 selectivity was enhanced from 25.4 to 34.7 simultaneously. Additionally, gas permeance increased but the selectivity decreased with the temperature increase, which followed the solution-diffusion based transport mechanism." @default.
- W2590881566 created "2017-03-03" @default.
- W2590881566 creator A5006575383 @default.
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- W2590881566 date "2017-01-01" @default.
- W2590881566 modified "2023-10-14" @default.
- W2590881566 title "Fabrication of Functionalized MOFs Incorporated Mixed Matrix Hollow Fiber Membrane for Gas Separation" @default.
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- W2590881566 doi "https://doi.org/10.1155/2017/2548957" @default.
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