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• W2591094787 abstract "Kanamycin is an antibiotic from the aminoglycoside class used to treat a myriad of infections. Aminoglycosides enhanced the photoluminescence of the thioglycolic acid modified CdTe quantum dots (TGA-CdTe QDs) following a Langmuir binding isotherm model. Binding constants were calculated indicating strong interactions between surface of nanoparticles and aminoglycosides. For kanamycin, the equilibrium binding constant was of 5.6 × 107 L mol−1. Based on this, a sensitive and selective method was developed for kanamycin determination based on the enhanced photoluminescence of TGA-CdTe QDs. Solid phase extraction with a new molecularly imprinted polymer, made using kanamycin as a template, provided high selectivity towards aminoglycosides. Under adjusted conditions, the two orders of magnitude analytical curve (linearized Langmuir binding isotherm) was constructed from 1.4 × 10−8 mol L−1 (limit of quantification) to 1.6 × 10−6 mol L−1 (8.1–92.8 ng mL−1) of kanamycin sulphate. The proposed procedure was tested for the determination of kanamycin in milk and yellow fever vaccine with recoveries between 86.6 and 93.7%. In addition, the kanamycin effect on TGA-CdTe QDs was also demonstrated under capillary electrophoresis regime, indicating another possibility for selective sensing." @default.
• W2591094787 created "2017-03-03" @default.
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• W2591094787 date "2017-07-01" @default.
• W2591094787 modified "2023-10-03" @default.
• W2591094787 title "Thioglycolic acid-CdTe quantum dots sensing and molecularly imprinted polymer based solid phase extraction for the determination of kanamycin in milk, vaccine and stream water samples" @default.
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• W2591094787 doi "https://doi.org/10.1016/j.snb.2017.02.117" @default.
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