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• W2591880991 abstract "Neptunium phosphide has the NaCl‐type structure with a lattice parameter of a = 5.610 A. The compound orders antiferromagnetically at 120°K. Between 120 and 74°K, the magnetic moments are arranged in a longitudinal sinusoidal modulation with the spin direction parallel to the cube axis, and with a constant repeat distance of 2.78±0.08 unit cells. Below 74°K the spin structure becomes commensurate with the lattice, having a repeat of 3 unit cells, and higher‐order harmonics in the neutron pattern indicate a tendency towards forming a square 3+, 3− wave. At 4.2°K, however, the process is incomplete, the two neptunium magnetic moments being 2.4 and 1.8 μg. The Mossbauer spectra at 4.2°K can be explained by assuming two different hyperfine fields of 3690±40 kOe and 4210±40 kOe at the Np site, with an occupation ratio of two to one. This interpretation is in agreement with the neutron results. Magnetization and resistivity measurements both indicate transitions at 120°K (TN), and 74°K. The resistivity falls sh..." @default.
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• W2591880991 date "1973-01-01" @default.
• W2591880991 modified "2023-09-26" @default.
• W2591880991 title "Magnetic Properties of Antiferromagnetic NpP" @default.
• W2591880991 doi "https://doi.org/10.1063/1.2947044" @default.
• W2591880991 hasPublicationYear "1973" @default.
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