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• W2592011500 abstract "Abstract The heat capacity of tetrakis(2,2,6,6-tetramethyl-3,5-heptanedionato)zirconium (Zr(C11H19O2)4) was measured over the temperature range (9–306) K by adiabatic-shield calorimetry and found to be without transitions or thermal anomalies. The data obtained were used to calculate its thermodynamic functions (entropy, enthalpy, reduced Gibbs energy) in the range (0–306) K. They have the following values at 298.15 K: C°p = (1195.7 ± 1.8) J·K−1·mol−1, Δ0298.15S°m = (1298 ± 3) J·K−1·mol−1, Δ0298.15H°m = (194.7 ± 0.3) kJ·mol−1, Φ°m = (645.2 ± 1.9) J·K−1·mol−1. The value of the absolute entropy were used to calculate the entropy of formation of Zr(C11H19O2)4 at T = 298.15 K." @default.
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• W2592011500 date "2017-07-01" @default.
• W2592011500 modified "2023-09-22" @default.
• W2592011500 title "Low-temperature heat capacity of tetrakis (2,2,6,6-tetramethyl-3,5-heptanedionato)zirconium" @default.
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• W2592011500 doi "https://doi.org/10.1016/j.jct.2017.02.026" @default.
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