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- W2592176119 abstract "Al−F bonds are among the most stable σ bonds known, exhibiting an even higher bond energy than Si−F bonds. Despite a stability advantage and a potentially high Lewis acidity of Al−F complexes, they have not been described as structurally defined catalysts for enantioselective reactions. We show that Al−F salen complexes with appended ammonium moieties give exceptional catalytic activity in asymmetric carboxycyanations. In addition to aromatic aldehydes, enal and aliphatic substrates are well accepted. Turnover numbers up to around 104 were achieved, whereas with previous catalysts 101–102 turnovers were typically attained. In contrast to Al−Me and Al−Cl salen complexes, the analogous Al−F species are remarkably stable towards air, water, and heat, and can be recovered unchanged after catalysis. They possess a considerably increased Lewis acidity as shown by DFT calculations." @default.
- W2592176119 created "2017-03-16" @default.
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- W2592176119 date "2017-03-01" @default.
- W2592176119 modified "2023-10-02" @default.
- W2592176119 title "An Aluminum Fluoride Complex with an Appended Ammonium Salt as an Exceptionally Active Cooperative Catalyst for the Asymmetric Carboxycyanation of Aldehydes" @default.
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- W2592176119 doi "https://doi.org/10.1002/anie.201612493" @default.
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