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• W2592308023 abstract "Abstract Submicron sized NaFePO 4 is successfully prepared in-situ by electrochemical delithiation of olivine type LiFePO 4 and subsequent sodium insertion in aprotic electrolyte. The composition dependence of the Gibbs energy and the entropy of sodiation is investigated by temperature dependent measurements of the equilibrium potential. The exchange current density and the sodium-ion diffusion coefficient of NaFePO 4 are systematically investigated as a function of the composition. Significant state of charge dependencies of the kinetic and thermodynamic parameters are found to correlate with phase transformations of the active material during charging and discharging. The results confirm the existence of a path dependence related to an asymmetric phase transformation behavior that was recently proposed in literature." @default.
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• W2592308023 date "2017-04-01" @default.
• W2592308023 modified "2023-09-26" @default.
• W2592308023 title "In-situ preparation and electrochemical characterization of submicron sized NaFePO4 cathode material for sodium-ion batteries" @default.
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• W2592308023 doi "https://doi.org/10.1016/j.electacta.2017.02.107" @default.
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