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- W2592352912 abstract "A novel 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)-mediated formal cycloaddition of β,γ-alkenyl esters with p-tolylsulfonylazide (p-TsN3) for the synthesis of 3,5-disubstituted pyrazoles has been developed. The reaction proceeded through diazotization of β,γ-alkenyl esters sequential with thermodynamic cyclization. p-Tolylsulfonylazide played a role as a source of two-nitrogen synthons. The reaction employs readily available starting materials, tolerates a wide range of functional groups, and proceeds under mild conditions." @default.
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- W2592352912 date "2017-04-01" @default.
- W2592352912 modified "2023-10-17" @default.
- W2592352912 title "Base-mediated formal [3+2] cycloaddition of β,γ-alkenyl esters and p-TsN3 for the synthesis of pyrazoles" @default.
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- W2592352912 doi "https://doi.org/10.1016/j.scib.2017.03.003" @default.
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