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- W2592385132 abstract "The temperature-dependent behavior within anionic phospho-Fries rearrangements (apFr) of P(O)(OFc)n(EAr)3–n (Fc = Fe(η5-C5H5)(η5-C5H4); E = O; Ar = phenyl, naphthyls, (R)-BINOL, [3]ferrocenophanyl; E = N, 1H-pyrrolyl, 1H-indolyl, 9H-carbazolyl; n = 1–3) is reported. While Fc undergoes one, the Ph-based apFr depends on temperature. First, the aryls are lithiated and rearranged, followed by Fc and N-heterocycles. Addition of Me2SO4 thus gave methylated Fc, contrary to non-organometallic aromatics giving mixtures of HO and MeO derivatives. The (R)-BINOL Fc phosphate gave Fc-rearranged phosphonate in 91% de. Exchanging O- with N-aliphatics prevented apFr, due to higher electron density at P. Also 1,2-N→C migrations were observed. X-ray analysis confirms 1D H bridge bonds for OH and NH derivatives. The differences in reactivity between N-aliphatic and N-aromatic phosphoramidates were verified by electrochemistry. The redox potentials revealed lower values for the electron-rich aliphatics, showing no apFr, preventing a nucleophilic attack at P after lithiation. Redox separations for multiple Fc molecules are based on electrostatic interactions." @default.
- W2592385132 created "2017-03-16" @default.
- W2592385132 creator A5000122909 @default.
- W2592385132 creator A5039877065 @default.
- W2592385132 creator A5088536141 @default.
- W2592385132 date "2017-03-07" @default.
- W2592385132 modified "2023-10-10" @default.
- W2592385132 title "Reactivity of Ferrocenyl Phosphates Bearing (Hetero-)Aromatics and [3]Ferrocenophanes toward Anionic Phospho-Fries Rearrangements" @default.
- W2592385132 cites W1186130538 @default.
- W2592385132 cites W1558007860 @default.
- W2592385132 cites W1589240236 @default.
- W2592385132 cites W1905815611 @default.
- W2592385132 cites W1964516234 @default.
- W2592385132 cites W1964777997 @default.
- W2592385132 cites W1966906288 @default.
- W2592385132 cites W1967533238 @default.
- W2592385132 cites W1968564692 @default.
- W2592385132 cites W1969238009 @default.
- W2592385132 cites W1969924821 @default.
- W2592385132 cites W1970029027 @default.
- W2592385132 cites W1973204268 @default.
- W2592385132 cites W1979251913 @default.
- W2592385132 cites W1981888349 @default.
- W2592385132 cites W1982277249 @default.
- W2592385132 cites W1983841280 @default.
- W2592385132 cites W1983892681 @default.
- W2592385132 cites W1986581735 @default.
- W2592385132 cites W1986942293 @default.
- W2592385132 cites W1987451855 @default.
- W2592385132 cites W1988839616 @default.
- W2592385132 cites W1990170643 @default.
- W2592385132 cites W1991683498 @default.
- W2592385132 cites W1991877453 @default.
- W2592385132 cites W1993730416 @default.
- W2592385132 cites W1997943966 @default.
- W2592385132 cites W2001362871 @default.
- W2592385132 cites W2005983381 @default.
- W2592385132 cites W2006596816 @default.
- W2592385132 cites W2009235519 @default.
- W2592385132 cites W2009946873 @default.
- W2592385132 cites W2010754245 @default.
- W2592385132 cites W2011271013 @default.
- W2592385132 cites W2016709039 @default.
- W2592385132 cites W2017526285 @default.
- W2592385132 cites W2018585677 @default.
- W2592385132 cites W2018904263 @default.
- W2592385132 cites W2020223335 @default.
- W2592385132 cites W2020539372 @default.
- W2592385132 cites W2022347975 @default.
- W2592385132 cites W2022673999 @default.
- W2592385132 cites W2024208100 @default.
- W2592385132 cites W2026840828 @default.
- W2592385132 cites W2026878080 @default.
- W2592385132 cites W2027912890 @default.
- W2592385132 cites W2028659561 @default.
- W2592385132 cites W2029494713 @default.
- W2592385132 cites W2029983339 @default.
- W2592385132 cites W2031171907 @default.
- W2592385132 cites W2033401000 @default.
- W2592385132 cites W2035330046 @default.
- W2592385132 cites W2039430165 @default.
- W2592385132 cites W2040338073 @default.
- W2592385132 cites W2041780347 @default.
- W2592385132 cites W2042109934 @default.
- W2592385132 cites W20428916 @default.
- W2592385132 cites W2044367058 @default.
- W2592385132 cites W2044403550 @default.
- W2592385132 cites W2045424919 @default.
- W2592385132 cites W2047923676 @default.
- W2592385132 cites W2049807213 @default.
- W2592385132 cites W2050397003 @default.
- W2592385132 cites W2060757838 @default.
- W2592385132 cites W2066652663 @default.
- W2592385132 cites W2066932188 @default.
- W2592385132 cites W2070134394 @default.
- W2592385132 cites W2071308593 @default.
- W2592385132 cites W2072457050 @default.
- W2592385132 cites W2072756002 @default.
- W2592385132 cites W2072794231 @default.
- W2592385132 cites W2073345376 @default.
- W2592385132 cites W2074815726 @default.
- W2592385132 cites W2075322883 @default.
- W2592385132 cites W2076541829 @default.
- W2592385132 cites W2077802490 @default.
- W2592385132 cites W2079865541 @default.
- W2592385132 cites W2080338399 @default.
- W2592385132 cites W2080470120 @default.
- W2592385132 cites W2080754160 @default.
- W2592385132 cites W2081994747 @default.
- W2592385132 cites W2085121368 @default.
- W2592385132 cites W2085339796 @default.
- W2592385132 cites W2087594399 @default.
- W2592385132 cites W2087795498 @default.
- W2592385132 cites W2089706156 @default.
- W2592385132 cites W2091190732 @default.
- W2592385132 cites W2091462151 @default.
- W2592385132 cites W2091735003 @default.
- W2592385132 cites W2096618384 @default.