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- W2592634495 abstract "The design of efficient radical photoinitiating systems requires a systematic and detailed evaluation of their photochemical characteristics. Correlating absorbance and the corresponding electronic transitions of a photoinitiator is critical for understanding its photoinduced reaction pathways. In the current contribution, we provide an in-depth investigation into the photochemistry and photophysics of two oxime ester derivatives (O-benzoyl-α-oxooxime, OXE01, and O-acetyloxime, OXE02), known for their excellent performance in pigmented formulations. In particular, we shed light on their wavelength-dependent photopolymerization properties. We utilized a combination of UV–vis spectroscopy, density functional theory (DFT) calculations, photochemically induced dynamic nuclear polarization spectroscopy (photo-CIDNP), and pulsed-laser polymerization with a wavelength-tunable laser with subsequent size exclusion chromatography coupled to high-resolution electrospray ionization mass spectrometry (PLP-SEC-ESI-MS) ..." @default.
- W2592634495 created "2017-03-16" @default.
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- W2592634495 date "2017-03-02" @default.
- W2592634495 modified "2023-10-17" @default.
- W2592634495 title "Wavelength-Dependent Photochemistry of Oxime Ester Photoinitiators" @default.
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- W2592634495 doi "https://doi.org/10.1021/acs.macromol.7b00089" @default.
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