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• W2592766538 abstract "We report the use of a chiral Cu(II) 3D metal-organic framework (MOF) based on the tripeptide Gly-l-His-Gly (GHG) for the enantioselective separation of metamphetamine and ephedrine. Monte Carlo simulations suggest that chiral recognition is linked to preferential binding of one of the enantiomers as a result of either stronger or additional H-bonds with the framework that lead to energetically more stable diastereomeric adducts. Solid-phase extraction of a racemic mixture by using Cu(GHG) as the extractive phase permits isolating >50% of the (+)-ephedrine enantiomer as target compound in only 4 min. To our knowledge, this represents the first example of a MOF capable of separating chiral polar drugs." @default.
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• W2592766538 date "2017-03-15" @default.
• W2592766538 modified "2023-10-17" @default.
• W2592766538 title "Peptide Metal–Organic Frameworks for Enantioselective Separation of Chiral Drugs" @default.
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• W2592766538 doi "https://doi.org/10.1021/jacs.7b00280" @default.
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