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- W2592835504 abstract "(Ge4Bi14)4− is the largest Bi-containing main-group polyanion that is not stabilized by ligands or endohedral atoms. Its structure comprises motifs from smaller polybismuthide anions, such as Bi73− or Bi113−, and clearly prefers the spatial separation of Bi atoms from a Ge4 waist in the center of the anion—unlike binary relatives with homologous element combinations that favor a maximum number of heteroatomic bonds. These findings, which were confirmed by DFT calculations, are described by S. Dehnen and R. J. Wilson in their Communication on page 3098 ff. (Ge4Bi14)4− is the largest Bi-containing main-group polyanion that is not stabilized by ligands or endohedral atoms. Its structure comprises motifs from smaller polybismuthide anions, such as Bi73− or Bi113−, and clearly prefers the spatial separation of Bi atoms from a Ge4 waist in the center of the anion—unlike binary relatives with homologous element combinations that favor a maximum number of heteroatomic bonds. These findings, which were confirmed by DFT calculations, are described by S. Dehnen and R. J. Wilson in their Communication on page 3098 ff. Metallocenes Supramolecular Chemistry Membrane Channels" @default.
- W2592835504 created "2017-03-16" @default.
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- W2592835504 date "2017-02-15" @default.
- W2592835504 modified "2023-09-27" @default.
- W2592835504 title "Cover Picture: (Ge4 Bi14 )4− : A Case of “Element Segregation” on the Molecular Level (Angew. Chem. Int. Ed. 11/2017)" @default.
- W2592835504 doi "https://doi.org/10.1002/anie.201701352" @default.
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