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- W2593389916 abstract "The release of NO by [Fe(NO)(Et2NpyS4)], where (Et2NpyS4)2− = 2,6-bis(2-mercaptophenylthiomethyl)-4-substituted pyridine(2-), has been studied in the absence and presence of a trapping agent. The results show that [Fe(NO)(Et2NpyS4)] releases NO spontaneously in solution with a slow rate, k-NO = 1.7 × 10−4 s−1 at 23 °C, in a reversible reaction. NO release becomes faster when the reaction intermediate [Fe(Et2 NpyS4)] was trapped by CO, thereby preventing the back reaction. The release of NO was studied as a function of CO concentration and temperature. The reported activation parameters, especially the positive activation entropy values for the release of NO, favor the operation of a dissociative interchange (Id) mechanism. Thus, [Fe(NO)(Et2NpyS4)] can serve as a NO deliverer." @default.
- W2593389916 created "2017-03-16" @default.
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- W2593389916 date "2017-03-20" @default.
- W2593389916 modified "2023-09-23" @default.
- W2593389916 title "Reversible release of nitric oxide from an iron(II) nitrosyl complex containing a biomimetic S<sub>4</sub>N chelate. A facile release of nitric oxide" @default.
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- W2593389916 doi "https://doi.org/10.1080/00958972.2017.1303680" @default.
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