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• W2593443307 abstract "Abstract In this study, three binary Mg–Ni alloys were prepared by gravity casting (GC) and mechanical alloying combined with spark plasma sintering (SPS). All samples were subjected to electrochemical hydriding in 6 mol/l KOH at 80 °C for 480 min. The structures and phase compositions of the samples were studied by optical and scanning electron microscopy, energy dispersive spectrometry and X-ray diffraction. The concentration of absorbed hydrogen was determined using an optical emission spectrometer with glow discharge for the GC alloys and using a hydrogen analyzer for the SPS alloys. The process of hydrogen evolution was observed by mass spectrometry for SPS alloys. The highest total amount of hydrogen was absorbed by the MgNi26 alloy both for both the GC and SPS alloys. The only hydriding product was MgH 2 in the α- and γ-modification. Compared to commercial powder MgH 2, the decomposition temperature was reduced by more than 200 °C, which can be ascribed to the catalytic effect of Mg 2 Ni and namely to the nanostructured magnesium formed after SPS." @default.
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• W2593443307 date "2017-09-01" @default.
• W2593443307 modified "2023-09-28" @default.
• W2593443307 title "Electrochemical hydriding of Mg–Ni alloys compacted by spark plasma sintering" @default.
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• W2593443307 doi "https://doi.org/10.1016/j.ijhydene.2017.02.142" @default.
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