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- W2593818897 abstract "An efficient diastereoselective approach to access trans-5-hydroxy-6-substituted 2-piperidinones skeleton has been developed through one-pot intramolecular tandem process of O-benzyl protected aldimine 11 with Grignard reagents. The diastereoselectivity of substitution at C-6 position of 2-piperidinone was controlled by α-benzyloxy group. In addition, the utility of this straightforward cascade process is demonstrated by the asymmetric syntheses of (+)-L-733, 060 (2) and its 2-substituted analogue 3, as well as (+)-CP-122721 (5)." @default.
- W2593818897 created "2017-03-16" @default.
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- W2593818897 date "2017-04-01" @default.
- W2593818897 modified "2023-10-17" @default.
- W2593818897 title "Divergent syntheses of L-733, 060 and CP-122721 from functionalized pieridinones made by one-pot tandem cyclization" @default.
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- W2593818897 doi "https://doi.org/10.1016/j.tet.2017.02.057" @default.
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