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- W2594553976 abstract "Vanadium (III) phosphate monoclinic VPO4·H2O was synthesized hydrothermally. The ɛ-VOPO4 nanosheets, formed by the oxidative de-intercalation of protons from monoclinic VPO4·H2O, can reversibly react with more than 1 mol lithium atoms in two steps. Crystal XRD analysis revealed that the structure of the ɛ-VOPO4 nanosheets is monoclinic with lattice parameters of α=7.2588(4) Å, b=6.8633(2) Å and c=7.2667(4) Å. The results show that the ɛ-VOPO4 nanosheets have a thickness of 200 nm and uniform crystallinity. Electrochemical characterization of the ɛ-VOPO4 monoclinic nanosheets reveals that they have good electrochemical properties at high current density, and deliver high initial capacity of 230.3 mA·h/g at a current density of 0.09 mA/cm2. Following the first charge cycle, reversible electrochemical lithium extraction/insertion at current density of 0.6 mA/cm2 affords a capacity retention rate of 73.6% (2.0–4.3 V window) that is stable for at least 1000 cycles." @default.
- W2594553976 created "2017-03-16" @default.
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- W2594553976 date "2017-02-01" @default.
- W2594553976 modified "2023-10-17" @default.
- W2594553976 title "Synthesis and characterization of ɛ -VOPO 4 nanosheets for secondary lithium-ion battery cathode" @default.
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- W2594553976 doi "https://doi.org/10.1016/s1003-6326(17)60042-6" @default.
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