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- W2594634319 abstract "Abstract The reaction of lithium guanidinate, Li[Pri2NC(NAr)2] (1, Ar = 2,6-diisopropylphenyl) with [ScCl3] at 80 °C for eight days and [LaBr3] at 50 °C overnight, in THF yields the mono-guanidinate complexes [Sc(Pri2NC(NAr)2(Cl)(μ-Cl)(LiCl-thf2)] (2) and [La(Pri2NC(NAr)2(μ-Br)2(LiBr-thf)2(LiBr-thf2)] (3). X-ray analysis shows that due to the varying sizes of the central metal atoms, one or three solvated Li salts are coordinated to Sc or La, respectively. In dinuclear compound 2, Sc is five coordinate and has a square pyramidal geometry while in compound 3, La shows a distorted octahedral coordination." @default.
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- W2594634319 date "2017-06-01" @default.
- W2594634319 modified "2023-09-26" @default.
- W2594634319 title "Mono-guanidinate complexes of scandium and lanthanum: Solvated alkali metal halides versus size of lanthanide" @default.
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- W2594634319 doi "https://doi.org/10.1016/j.ica.2017.03.014" @default.
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