Matches in SemOpenAlex for { <https://semopenalex.org/work/W2594831191> ?p ?o ?g. }
- W2594831191 endingPage "10" @default.
- W2594831191 startingPage "1" @default.
- W2594831191 abstract "Calcium phosphate (CP) nanoparticles were synthesized in choline chloride-urea deep eutectic solvent (DES). The effect of synthesis time and temperature on crystallinity, particulate properties, and elemental/chemical purity of the CP nanoparticles were investigated by X-ray diffraction, field emission scanning electron microscopy, energy dispersive X-ray spectroscopy, and Fourier transform infra-red spectroscopy. The results confirmed the formation of amorphous calcium phosphate (ACP) nanoparticles (at 25 °C for 10 min) with spherical morphology, mean diameter of 29 nm, and high elemental-structural purity. The increase of synthesis time from 10 min to 48 h at 25 °C had no significant influence on the phase transformation of ACP nanoparticle so that the nanoparticles showed high degree of amorphization after 48 h. The crystallization of particles rapidly rose upon increase of the synthesis temperature so that the nanoparticles of calcium-deficient hydroxyapatite (CDHA) with percent crystallinity of ~ 97% were obtained in choline chloride-urea DES at 150 °C after 24 h. Kinetic and thermodynamic studies revealed that upon increase of temperature from 25 to 150 °C, the rate constant and Gibbs free energy for growth of CP crystals in the DES rises from 8.70 × 10− 4 to 1.37 × 10− 3 min− 1 and 3.22 × 10+ 2 to 4.57 × 10+ 2 KJ·mol− 1, respectively." @default.
- W2594831191 created "2017-03-16" @default.
- W2594831191 creator A5016518496 @default.
- W2594831191 creator A5035422302 @default.
- W2594831191 creator A5073228325 @default.
- W2594831191 creator A5081200340 @default.
- W2594831191 date "2017-05-01" @default.
- W2594831191 modified "2023-09-27" @default.
- W2594831191 title "Time and temperature mediated evolution of CDHA from ACP nanoparticles in deep eutectic solvents: Kinetic and thermodynamic considerations" @default.
- W2594831191 cites W1446554341 @default.
- W2594831191 cites W1615662518 @default.
- W2594831191 cites W1964343099 @default.
- W2594831191 cites W1964610568 @default.
- W2594831191 cites W1967410318 @default.
- W2594831191 cites W1969191682 @default.
- W2594831191 cites W1974562872 @default.
- W2594831191 cites W1975853152 @default.
- W2594831191 cites W1985843317 @default.
- W2594831191 cites W1995042530 @default.
- W2594831191 cites W1998820551 @default.
- W2594831191 cites W2003546676 @default.
- W2594831191 cites W2004215242 @default.
- W2594831191 cites W2006631866 @default.
- W2594831191 cites W2010430654 @default.
- W2594831191 cites W2016065249 @default.
- W2594831191 cites W2022902905 @default.
- W2594831191 cites W2023095569 @default.
- W2594831191 cites W2029220059 @default.
- W2594831191 cites W2036037715 @default.
- W2594831191 cites W2045895387 @default.
- W2594831191 cites W2049689659 @default.
- W2594831191 cites W2052345938 @default.
- W2594831191 cites W2053433405 @default.
- W2594831191 cites W2070855078 @default.
- W2594831191 cites W2075755484 @default.
- W2594831191 cites W2077737172 @default.
- W2594831191 cites W2081222446 @default.
- W2594831191 cites W2083258682 @default.
- W2594831191 cites W2083456714 @default.
- W2594831191 cites W2087989742 @default.
- W2594831191 cites W2092145947 @default.
- W2594831191 cites W2098639113 @default.
- W2594831191 cites W2140073203 @default.
- W2594831191 cites W2179434303 @default.
- W2594831191 cites W2270535388 @default.
- W2594831191 cites W2314404257 @default.
- W2594831191 cites W2316285774 @default.
- W2594831191 cites W2328643385 @default.
- W2594831191 cites W2329984730 @default.
- W2594831191 cites W2331472033 @default.
- W2594831191 cites W2332246339 @default.
- W2594831191 cites W2332701423 @default.
- W2594831191 cites W2341160634 @default.
- W2594831191 cites W859550568 @default.
- W2594831191 doi "https://doi.org/10.1016/j.matdes.2017.02.076" @default.
- W2594831191 hasPublicationYear "2017" @default.
- W2594831191 type Work @default.
- W2594831191 sameAs 2594831191 @default.
- W2594831191 citedByCount "12" @default.
- W2594831191 countsByYear W25948311912018 @default.
- W2594831191 countsByYear W25948311912019 @default.
- W2594831191 countsByYear W25948311912021 @default.
- W2594831191 countsByYear W25948311912022 @default.
- W2594831191 countsByYear W25948311912023 @default.
- W2594831191 crossrefType "journal-article" @default.
- W2594831191 hasAuthorship W2594831191A5016518496 @default.
- W2594831191 hasAuthorship W2594831191A5035422302 @default.
- W2594831191 hasAuthorship W2594831191A5073228325 @default.
- W2594831191 hasAuthorship W2594831191A5081200340 @default.
- W2594831191 hasConcept C121332964 @default.
- W2594831191 hasConcept C127413603 @default.
- W2594831191 hasConcept C13965031 @default.
- W2594831191 hasConcept C146477669 @default.
- W2594831191 hasConcept C147438087 @default.
- W2594831191 hasConcept C155672457 @default.
- W2594831191 hasConcept C159985019 @default.
- W2594831191 hasConcept C160892712 @default.
- W2594831191 hasConcept C171250308 @default.
- W2594831191 hasConcept C178790620 @default.
- W2594831191 hasConcept C18168003 @default.
- W2594831191 hasConcept C185592680 @default.
- W2594831191 hasConcept C191897082 @default.
- W2594831191 hasConcept C192562407 @default.
- W2594831191 hasConcept C203036418 @default.
- W2594831191 hasConcept C26771246 @default.
- W2594831191 hasConcept C2777001299 @default.
- W2594831191 hasConcept C2778375661 @default.
- W2594831191 hasConcept C2780371645 @default.
- W2594831191 hasConcept C42360764 @default.
- W2594831191 hasConcept C46275449 @default.
- W2594831191 hasConcept C519063684 @default.
- W2594831191 hasConcept C56052488 @default.
- W2594831191 hasConcept C8010536 @default.
- W2594831191 hasConcept C87976508 @default.
- W2594831191 hasConcept C97355855 @default.
- W2594831191 hasConceptScore W2594831191C121332964 @default.
- W2594831191 hasConceptScore W2594831191C127413603 @default.
- W2594831191 hasConceptScore W2594831191C13965031 @default.