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- W2595414504 abstract "Abstract Isocyanides are exceptional building blocks, the wide deployment of which in multicomponent and metal‐insertion reactions belies their limited availability. The first conjugate addition/alkylation to alkenyl isocyanides is described, which addresses this deficiency. An array of organolithiums, magnesiates, enolates, and metalated nitriles add conjugately to β‐ and β,β‐disubstituted arylsulfonyl alkenyl isocyanides to rapidly assemble diverse isocyanide scaffolds. The intermediate metalated isocyanides are efficiently trapped with electrophiles to generate substituted isocyanides incorporating contiguous tri‐ and tetra‐substituted centers. The substituted isocyanides are ideally functionalized for elaboration into synthetic targets as illustrated by the three‐step synthesis of γ‐carboline N ‐methyl ingenine B." @default.
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- W2595414504 date "2017-03-13" @default.
- W2595414504 modified "2023-10-18" @default.
- W2595414504 title "Alkenyl Isocyanide Conjugate Additions: A Rapid Route to γ-Carbolines" @default.
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- W2595414504 doi "https://doi.org/10.1002/anie.201612574" @default.
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