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• W2595463719 abstract "Herein, we elucidate the impact of tubular confinement on the structure and relaxation behavior of poly(vinylidene difluoride) (PVDF) and how these affect the para-/ferroelectric behavior of this polymer. We use PVDF nanotubes that were solidified in anodic aluminum oxide (AAO) templates. Dielectric spectroscopy measurements evidence a bimodal relaxation process for PVDF nanotubes: besides the bulk-like α-relaxation, we detect a notably slower relaxation that is associated with the PVDF regions of restricted dynamics at the interface with the AAO pore. Strikingly, both the bulk-like and the interfacial relaxation tend to become temperature independent as the temperature increases, a behavior that has been observed before in inorganic relaxor ferroelectrics. In line with this, we observe that the real part of the dielectric permittivity of the PVDF nanotubes exhibits a broad maximum when plotted against the temperature, which is, again, a typical feature of relaxor ferroelectrics. As such, we propose that, in nanotubular PVDF, ferroelectric-like nanodomains are formed in the amorphous phase regions adjacent to the AAO interface. These ferroelectric nanodomains may result from an anisotropic chain conformation and a preferred orientation of local dipoles due to selective H-bond formation between the PVDF macromolecues and the AAO walls. Such relaxor-ferroelectric-like behavior has not been observed for nonirradiated PVDF homopolymer; our findings thus may enable in the future alternative applications for this bulk commodity plastic, e.g., for the production of electrocaloric devices for solid-state refrigeration which benefit from a relaxor-ferroelectric-like response." @default.
• W2595463719 created "2017-03-23" @default.
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• W2595463719 date "2017-04-03" @default.
• W2595463719 modified "2023-10-13" @default.
• W2595463719 title "Relaxations and Relaxor-Ferroelectric-Like Response of Nanotubularly Confined Poly(vinylidene fluoride)" @default.
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• W2595463719 doi "https://doi.org/10.1021/acs.chemmater.6b05391" @default.
• W2595463719 hasPublicationYear "2017" @default.
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