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- W2595772105 abstract "Described herein is the reaction of the first-generation Grubbs catalyst RuCl2(PCy3)2(=CHPh) (GI) with free IMe4 (1,3,4,5-tetramethylimidazol-2-ylidene), in which the N-mesityl groups commonly present in Ru-NHC metathesis catalysts are truncated to N-Me (NHC = N-heterocyclic carbene). Treatment of GI with IMe4 (1–2.1 equiv) effects displacement of both PCy3 ligands, but does not terminate at the mono-ruthenium species RuCl2(IMe4)2(=CHPh) Ru-3. Instead, dimerization occurs to afford [Ru2(μ-Cl)3(IMe4)4(=CHPh)2]Cl Ru-4, the structure of which was confirmed by crystallographic analysis. A molecular dynamics study of Ru-4 indicated rapid rotation of both the NHC and the benzylidene ligands, accounting for the observation of multiple benzylidene signals in the solution 1H NMR spectrum of Ru-4." @default.
- W2595772105 created "2017-03-23" @default.
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- W2595772105 date "2017-10-01" @default.
- W2595772105 modified "2023-09-26" @default.
- W2595772105 title "Synthesis and dynamic behaviour of a dimeric ruthenium benzylidene complex bearing a truncated N-heterocyclic carbene ligand" @default.
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- W2595772105 doi "https://doi.org/10.1016/j.jorganchem.2017.03.033" @default.
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