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- W2596804543 abstract "Abstract Phenolic-oil can be upgraded by etherification with methanol to decrease the polarity and acidity of the product oil. However, alkoxy phenols have an inhibiting effect to the etherification of alkyl phenols in the phenolic mixture. So, it is very important to produce alkyl phenols with high selectivity and extremely low content of alkoxy phenols, through a catalytic pyrolytic process. Herein, the effects of HZSM-5, NaY, and KH 2 PO 4 /AA (KH 2 PO 4 loaded on activated Al 2 O 3 ) on the pyrolysis of corn straw fermentation residue are investigated, for producing alkyl phenols high efficiently. KH 2 PO 4 /AA is found to be the best catalyst in promoting the formation of alkyl phenols and in inhibiting alkoxy phenols. Under the catalysis of KH 2 PO 4 /AA, the tar yield increases with rising temperature, and reaches to the maximum tar yield of 13.7% at 500 °C, and then declines with further increasing temperature. The tar obtained under optimized reaction conditions, nearly consists of 50% of alkyl phenols and over 23% of aliphatic hydrocarbons with zero content of alkoxy phenols. K 3 Al 2 (PO 4 ) 3 is generated from the solid phase reaction between KH 2 PO 4 and Al 2 O 3 , through which alkoxy phenols can be high selectively adsorbed and activated, and thus leads to the formation of alkyl phenols." @default.
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- W2596804543 date "2017-08-01" @default.
- W2596804543 modified "2023-09-24" @default.
- W2596804543 title "Catalytic pyrolysis of corn straw fermentation residue for producing alkyl phenols" @default.
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- W2596804543 doi "https://doi.org/10.1016/j.renene.2017.03.060" @default.
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