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• W2596818974 endingPage "e21386" @default.
• W2596818974 startingPage "e21386" @default.
• W2596818974 abstract "We discuss from the perspective of relaxation dynamics the feasibility of recording NMR spectra of 33S nuclei bound to cross-link junctions in cross-linked elastomers (i.e. vulcanized rubber). Assuming the quadrupolar relaxation mechanism due to fluctuating electric field gradients, the calculations of transverse and longitudinal 33S relaxation times encompassing a large range of correlation times, static magnetic fields, and quadrupolar coupling constants reveal that both relaxation processes will constitute significant bottlenecks in recording the 33S spectra of cross-linked elastomers inherently endowed with a large distribution of motional modes. In the rubbery state, the observable 33S NMR signal will result from motionally averaged, central transition magnetization of the 33S nuclei in cross-link junctions involved in large amplitude, high-frequency motions." @default.
• W2596818974 created "2017-03-23" @default.
• W2596818974 creator A5026909899 @default.
• W2596818974 creator A5079177839 @default.
• W2596818974 date "2016-03-01" @default.
• W2596818974 modified "2023-09-25" @default.
• W2596818974 title "Toward recording 33 S NMR spectra of cross-linked elastomers: Relaxation dynamics perspective" @default.
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• W2596818974 doi "https://doi.org/10.1002/cmr.a.21386" @default.
• W2596818974 hasPublicationYear "2016" @default.
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