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- W2597212962 abstract "Carbon is a versatile building element of many interestingmaterials that have already find practical applications in theform of thin films (diamond, DLC) or potential applications inthe form of nanostructures (fullerenes, carbon nanotubes,graphene). For electronics or sensors, it is important toprovide a very good contact to the functional structures. Goldis the best choice taking into account its inertness, i.e.oxidation resistance. From this point of view the investigationof the growth of carbon materials on gold is important.However, the interaction of hydrogen and hydrocarbon plasmasand growing carbon material with an inert gold surface is ofhigh interest in basic research too. Amorphous hydrocarbonfilms and carbon nanotubes (CNTs) were prepared on goldsubstrate by means of plasma enhanced chemical vapor deposition(PECVD) and thermal CVD for comparison. Thin iron film (5 nm)was used as catalyst in case of CNTs synthesis. Three types ofdischarges were employed for this study, namely (i) a lowpressure (8 kPa) dual frequency discharge (2.45 GHz and 13.56MHz) in the mixture of H2 and CH4; (ii) a capillary plasma jetoperating at 27.12 MHz in Ar/H2/CH4 gas mixture; (iii) amicrowave torch (2.45 GHz) at atmospheric pressure inAr/H2/CH4. The low and atmospheric pressure thermal CVDproceeded in the same gas mixtures as above. The surfacemorphology of the deposits was investigated by a highresolution scanning electron microscopy (HRSEM) and structureprofiles were observed with a help of focused ion beamablation. Laser desorption ionization (LDI) combined withtime-of-flight mass spectrometry and infrared reflectionabsorption spectroscopy (IRRAS) were applied to study chemicalcomposition. A creation of rarely observed gold-relatedclusters was observed by LDI and related to infrared absorptionpeaks." @default.
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- W2597212962 date "2012-10-09" @default.
- W2597212962 modified "2023-09-27" @default.
- W2597212962 title "Growth of Carbon Materials on Gold Substrate by Plasma Enhanced CVD" @default.
- W2597212962 doi "https://doi.org/10.3384/wcc2/395-398" @default.
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