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- W2597397740 abstract "Abstract A novel visible-light-active CdS@g-C 3 N 4 photocatalyst was synthesized via a chemisorption method. This core@shell structure catalyst exhibited enhanced photocatalytic H 2 production activity under visible-light (λ ≥ 420 nm) irradiation. The nano-sheet g-C 3 N 4 was successfully coated on CdS nanoparticles with intimate contact. When the content of g-C 3 N 4 in the hybridized composite is 3 wt. %, the hydrogen-production rate of the CdS@g-C 3 N 4 is 2.5 and 2.2 times faster than pure CdS and bulk g-C 3 N 4 , respectively. Superior stability was also observed in the cyclic runs. The improvement in stability and activity result from the ability of the π-conjugated g-C 3 N 4 material in transporting photo-induced holes. The core@shell structure promoted separation of the photo-generated electron-hole pair and accelerated the emigration speed of the hole from the valence band of CdS. This effect also results in a greatly improved amount of hydrogen production. The possible mechanism for the photocatalytic activity and stability of CdS@g-C 3 N 4 are tentatively proposed." @default.
- W2597397740 created "2017-03-23" @default.
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- W2597397740 date "2017-07-01" @default.
- W2597397740 modified "2023-09-26" @default.
- W2597397740 title "Increased photocatalytic hydrogen evolution and stability over nano-sheet g-C3N4 hybridized CdS core@shell structure" @default.
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- W2597397740 doi "https://doi.org/10.1016/j.ijhydene.2017.02.171" @default.
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