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- W2597474790 abstract "In crystal structural databases one finds here and there structures in which a transition metal atom is encoded as mono- or zero-coordinated, a situation that one might expect only in the gas phase, but not in solution or in the solid state. In some instances such an assignment is unavoidable due, e.g., to the presence of disorder in the metal coordination sphere that makes the determination of a coordination number impossible. In other cases, the lack of attribution of a coordination number (in practice encoded as zero-coordination) may result from the complexity of the crystal structure, or from the consideration of the transition metal atom as an independent cation, as usually done for highly ionic species such as the alkaline and alkaline-earth metal compounds. Here, a closer structural analysis is carried out on such low-coordinated metals, and some interesting geometrical and bonding features are found, such as the first chemical structure recognized to have the shape of the elongated square cupola, a 20 vertices Johnson polyhedron." @default.
- W2597474790 created "2017-04-07" @default.
- W2597474790 creator A5024602124 @default.
- W2597474790 date "2018-01-01" @default.
- W2597474790 modified "2023-10-17" @default.
- W2597474790 title "Zero- and mono-coordinate transition metals in crystal structures: A box full of surprises" @default.
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- W2597474790 doi "https://doi.org/10.1016/j.ica.2017.03.036" @default.
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