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- W2597680147 abstract "Entropy scaling is an intriguingly simple approach for correlating and predicting transport properties of real substances and mixtures. It is convincingly documented in the literature that entropy scaling is indeed a firm concept for the shear viscosity of real substances, including hydrogen bonding species and strongly nonspherical species. We investigate whether entropy scaling is applicable for thermal conductivity. It is shown that the dimensionless thermal conductivity (thermal conductivity divided by a reference thermal conductivity) does not show a single-variable dependence on residual entropy, for obvious choices of a reference thermal conductivity. We perform a detailed analysis of experimental data and propose a reference thermal conductivity that is itself a simple function of the residual entropy. We then obtain good scaling behavior for the entire fluid region for water and 147 organic substances from various chemical families: linear and branched alkanes, alkenes, aldehydes, aromatics, ethe..." @default.
- W2597680147 created "2017-04-07" @default.
- W2597680147 creator A5004283404 @default.
- W2597680147 creator A5067171501 @default.
- W2597680147 date "2017-04-05" @default.
- W2597680147 modified "2023-09-24" @default.
- W2597680147 title "Thermal Conductivity of Real Substances from Excess Entropy Scaling Using PCP-SAFT" @default.
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- W2597680147 doi "https://doi.org/10.1021/acs.iecr.6b04289" @default.
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