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- W2597792493 abstract "Bi-functional metal (Ni and Co)/zeolite catalysts were designed to upgrade palmitic acid. No isomerization products were observed over parent zeolitic supports H-ZSM-5 without metal phase, but hydrodeoxygenation (minor route), hydrodecarbonylation (major route) and the direct cracking were observed. On one hand, the impregnation of Ni or Co species, enhanced hydrodeoxygenation via hydration-hygenation route and decreased hydrodecarbonylation route. On the other hand, metal phase decreased the isomerization temperature, which is consistent with enhanced the acidic strength of whole bi-functional catalysts especially for Co/zeolite catalysts. Simultaneous deoxygenation of palmitic acid, isomerization of hydrogenated products and cracking were achieved over bi-functional Ni/H-ZSM-5 and Co/H-ZSM-5 catalysts, with more C16 and iso-products formation. Furthermore, the introduction of mesopores obviously enhanced iso-products and C16 formation for Co-based catalysts." @default.
- W2597792493 created "2017-04-07" @default.
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- W2597792493 date "2017-07-01" @default.
- W2597792493 modified "2023-10-16" @default.
- W2597792493 title "Tailoring product distribution during upgrading of palmitic acid over bi-functional metal/zeolite catalysts" @default.
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- W2597792493 doi "https://doi.org/10.1016/j.ces.2017.03.052" @default.
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