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- W2598112090 abstract "O6-Corona[3]arene[3]tetrazines with expanded cavities were synthesized by one-pot SNAr reaction between 3,6-dichlorotetrazine and aromatic diols. The macrocycle-to-macrocycle transformation involving IEDDA of tetrazine moieties with an enamine followed by denitrogenative aromatization afforded O6-corona[3]arene[3]pyridazines. O6-Corona[6]arenes adopted coronary conformations yielding hexagonal cavities of varied sizes. While O6-corona[3]arene[3]pyridazines complexed both C60 and C70 in a virtually nonselective manner, O6-corona[3]arene[3]tetrazines behaved as selective receptors to complex C70 with K1:1 values up to (3.98 ± 0.08) × 104 M–1 in toluene." @default.
- W2598112090 created "2017-04-07" @default.
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- W2598112090 date "2017-03-21" @default.
- W2598112090 modified "2023-10-17" @default.
- W2598112090 title "O<sub>6</sub>-Corona[6]arenes with Expanded Cavities for Specific Complexation with C<sub>70</sub>" @default.
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- W2598112090 doi "https://doi.org/10.1021/acs.orglett.7b00409" @default.
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