Matches in SemOpenAlex for { <https://semopenalex.org/work/W2598598498> ?p ?o ?g. }
- W2598598498 endingPage "7793" @default.
- W2598598498 startingPage "7782" @default.
- W2598598498 abstract "The adsorption behavior of three chlorinated methane derivative molecules, CH3Cl, CHCl3, and CCl4, is investigated at the (0001) surface of Ih ice at the tropospheric temperature of 200 K by means of grand canonical Monte Carlo simulations. This study completes our earlier investigations concerning the adsorption of CH4, CH2Cl2, and fluorinated methane derivatives. Our results show that neither CHCl3 nor CCl4 exhibits any adsorption. This complete lack of adsorption is attributed to the interplay of the very strong cohesion acting between the adsorbate molecules, and their relatively weak interaction with the ice phase. By contrast, CH3Cl does exhibit a noticeable adsorption on ice, and the adsorbed molecules prefer to turn toward the ice surface by their H atoms, forming weak, C–H····O-type hydrogen bonds with surface waters. The lateral (i.e., adsorbate–adsorbate) contribution to the total interaction energy of the adsorbed molecules is always considerably larger (in magnitude) than in the case of the corresponding fluorinated analogues, making also the total adsorption energy lower for the chlorinated molecules than for their fluorinated counterpart. As a consequence of this strong attraction between the chlorinated adsorbate molecules, their condensation occurs at lower chemical potential (and, hence, pressure) values than that of the fluorinated analogues, which prevents the formation or completion of the adsorption layer of the chlorinated molecules." @default.
- W2598598498 created "2017-04-07" @default.
- W2598598498 creator A5004794301 @default.
- W2598598498 creator A5033897543 @default.
- W2598598498 creator A5076114807 @default.
- W2598598498 date "2017-03-31" @default.
- W2598598498 modified "2023-10-16" @default.
- W2598598498 title "Adsorption of Chlorinated Methane Derivatives at the Ice Surface: A Grand Canonical Monte Carlo Simulation Study" @default.
- W2598598498 cites W1217142152 @default.
- W2598598498 cites W1852659621 @default.
- W2598598498 cites W1966786704 @default.
- W2598598498 cites W1967541803 @default.
- W2598598498 cites W1968318097 @default.
- W2598598498 cites W1971556338 @default.
- W2598598498 cites W1981419280 @default.
- W2598598498 cites W1986230696 @default.
- W2598598498 cites W1986660156 @default.
- W2598598498 cites W1990611439 @default.
- W2598598498 cites W1991261241 @default.
- W2598598498 cites W1992279774 @default.
- W2598598498 cites W1993908194 @default.
- W2598598498 cites W1997492218 @default.
- W2598598498 cites W1999218232 @default.
- W2598598498 cites W2000378786 @default.
- W2598598498 cites W2000648149 @default.
- W2598598498 cites W2003828025 @default.
- W2598598498 cites W2006451145 @default.
- W2598598498 cites W2009626022 @default.
- W2598598498 cites W2010827259 @default.
- W2598598498 cites W2012804596 @default.
- W2598598498 cites W2015798177 @default.
- W2598598498 cites W2026109536 @default.
- W2598598498 cites W2026692362 @default.
- W2598598498 cites W2027473783 @default.
- W2598598498 cites W2029982123 @default.
- W2598598498 cites W2032376311 @default.
- W2598598498 cites W2032598923 @default.
- W2598598498 cites W2035590023 @default.
- W2598598498 cites W2037634184 @default.
- W2598598498 cites W2039348456 @default.
- W2598598498 cites W2040203177 @default.
- W2598598498 cites W2044537406 @default.
- W2598598498 cites W2046953613 @default.
- W2598598498 cites W2053164863 @default.
- W2598598498 cites W2055341112 @default.
- W2598598498 cites W2055519538 @default.
- W2598598498 cites W2056760934 @default.
- W2598598498 cites W2058777775 @default.
- W2598598498 cites W2060657900 @default.
- W2598598498 cites W2063084938 @default.
- W2598598498 cites W2063240164 @default.
- W2598598498 cites W2079054569 @default.
- W2598598498 cites W2080136965 @default.
- W2598598498 cites W2080295455 @default.
- W2598598498 cites W2080527541 @default.
- W2598598498 cites W2081782871 @default.
- W2598598498 cites W2083021836 @default.
- W2598598498 cites W2083454726 @default.
- W2598598498 cites W2085017152 @default.
- W2598598498 cites W2087596773 @default.
- W2598598498 cites W2090961311 @default.
- W2598598498 cites W2093907098 @default.
- W2598598498 cites W2094143219 @default.
- W2598598498 cites W2094231068 @default.
- W2598598498 cites W2117396433 @default.
- W2598598498 cites W2122425162 @default.
- W2598598498 cites W2125871189 @default.
- W2598598498 cites W2126424108 @default.
- W2598598498 cites W2129838949 @default.
- W2598598498 cites W2138255925 @default.
- W2598598498 cites W2139440262 @default.
- W2598598498 cites W2147993766 @default.
- W2598598498 cites W2150264253 @default.
- W2598598498 cites W2159683864 @default.
- W2598598498 cites W2167385231 @default.
- W2598598498 cites W2169970383 @default.
- W2598598498 cites W2170735318 @default.
- W2598598498 cites W2273200454 @default.
- W2598598498 cites W2313120275 @default.
- W2598598498 cites W2314104404 @default.
- W2598598498 cites W2317356403 @default.
- W2598598498 cites W2329128489 @default.
- W2598598498 cites W2467846614 @default.
- W2598598498 cites W2470245691 @default.
- W2598598498 cites W3033358318 @default.
- W2598598498 cites W4249707520 @default.
- W2598598498 cites W4301956075 @default.
- W2598598498 doi "https://doi.org/10.1021/acs.jpcc.6b11710" @default.
- W2598598498 hasPublicationYear "2017" @default.
- W2598598498 type Work @default.
- W2598598498 sameAs 2598598498 @default.
- W2598598498 citedByCount "8" @default.
- W2598598498 countsByYear W25985984982018 @default.
- W2598598498 countsByYear W25985984982019 @default.
- W2598598498 countsByYear W25985984982020 @default.
- W2598598498 countsByYear W25985984982022 @default.
- W2598598498 countsByYear W25985984982023 @default.
- W2598598498 crossrefType "journal-article" @default.