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- W2599192015 abstract "Cationic 1-aza-2-azoniaallene salts react with structurally constrained alkenes in intramolecular reactions by C-H insertion at the allylic position, or by (2+1)-cycloaddition with the alkene followed by ring opening. The latter reaction gives further evidence of the nitrenium-like character of 1-aza-2-azoniaallene salts. DFT calculations show that alkene addition is intrinsically more favorable, but that predistortion can lead to C-H insertion." @default.
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- W2599192015 date "2017-03-27" @default.
- W2599192015 modified "2023-10-17" @default.
- W2599192015 title "(2+1)-Cycloaddition Reactions Give Further Evidence of the Nitrenium-like Character of 1-Aza-2-azoniaallene Salts" @default.
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- W2599192015 doi "https://doi.org/10.1021/acs.joc.7b00407" @default.
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