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- W2599492022 abstract "Abstract Natural (−)-menthol was applied to construction of mono-N-tosylated-1,2-diamine derivatives. The O-tosylation and elimination of the tosylate of the menthol intermediate led to trans-p-menth-2-ene. The unsaturated menth-2-ene was next transformed into a mixture of N-tosylaziridines, which upon reaction with sodium azide gave four isomeric azides. The reduction of the formed tosylazides on Pd/C gave new chiral mono-N-tosylated-1,2-diamines, which were used as ligands in the asymmetric transfer hydrogenation protocol on aromatic ketones and endocyclic imine." @default.
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- W2599492022 date "2017-04-01" @default.
- W2599492022 modified "2023-09-23" @default.
- W2599492022 title "New N , N -diamine ligands derived from (−)-menthol and their application in the asymmetric transfer hydrogenation" @default.
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- W2599492022 doi "https://doi.org/10.1016/j.tetasy.2017.02.012" @default.
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