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- W2599675639 abstract "We designed a novel tricobalt(III) metallo-molecular cage in which its apertures can be closed with bifunctional ligands via coordination bonds. A closed-cage complex was easily formed by ligand exchange of its open-cage analogue. Guest uptake/release by the open-cage complex was sufficiently fast to quickly reach guest-binding equilibrium, while that by the closed-cage complex was extremely slow and took about 1 week to reach equilibrium. The guest uptake was retarded by at least 2000 times by introduction of the bifunctional ligands at the cage apertures." @default.
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- W2599675639 date "2017-03-24" @default.
- W2599675639 modified "2023-10-17" @default.
- W2599675639 title "A Metallo-molecular Cage That Can Close the Apertures with Coordination Bonds" @default.
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- W2599675639 doi "https://doi.org/10.1021/jacs.7b00840" @default.
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