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- W2599684595 abstract "Abstract A novel double‐anion complex, H 13 [(CH 3 ) 4 N] 12 [PNb 12 O 40 (V V O) 2 ⋅(V IV 4 O 12 ) 2 ]⋅22 H 2 O ( 1 ), based on bicapped polyoxoniobate and tetranuclear polyoxovanadate was synthesized, characterized by routine techniques and used in the catalytic decontamination of chemical warfare agents. Under mild conditions, 1 catalyzes both hydrolysis of the nerve agent simulant, diethyl cyanophosphonate (DECP) and selective oxidation of the sulfur mustard simulant, 2‐chloroethyl ethyl sulfide (CEES). In the oxidative decontamination system 100 % CEES was transformed selectively to nontoxic 2‐chloroethyl ethyl sulfoxide and vinyl ethyl sulfoxide using nearly stoichiometric 3 % aqueous H 2 O 2 with a turnover frequency (TOF) of 16 000 h −1 . Importantly, the catalytic activity is maintained even after ten recycles and CEES is completely decontaminated in 3 mins without formation of the highly toxic sulfone by‐product. A three‐step oxidative mechanism is proposed." @default.
- W2599684595 created "2017-04-07" @default.
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- W2599684595 date "2017-03-21" @default.
- W2599684595 modified "2023-10-10" @default.
- W2599684595 title "A Polyoxoniobate-Polyoxovanadate Double-Anion Catalyst for Simultaneous Oxidative and Hydrolytic Decontamination of Chemical Warfare Agent Simulants" @default.
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- W2599684595 doi "https://doi.org/10.1002/ange.201700159" @default.
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