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- W2599685570 abstract "A novel [email protected](Fe) (DOBDC: 2,5-dioxido-1,4-benzenedicarboxylate) was successfully synthesized by grafting DOBDC to MIL-100(Fe) via a one-pot synthesis. The resultant [email protected](Fe) was characterized and tested for their selective CO2 adsorption performance. Results showed that the resultant [email protected](Fe) exhibited a 62% improved CO2 capacity compared to that of MIL-100(Fe) at room temperature and 1 bar, and its CO2/N2 adsorption selectivity was up to 50 at ambient condition, being 8 times higher when compared to MIL-100(Fe). CO2-TPD curve of [email protected](Fe) exhibited two desorption peaks, while that of MIL-100(Fe) exhibited only one peak, confirming that a new type of CO2 adsorption sites was created in [email protected](Fe) due to introduction of DOBDC, which resulted in the enhanced CO2 capacity of [email protected](Fe). Besides, [email protected](Fe) showed excellent moisture-stability after being exposed to 90% relative humidity for 30 days. The improved CO2 capacity and decent steam stability of [email protected](Fe) will make it very promising in potential practical application of CO2 capture." @default.
- W2599685570 created "2017-04-07" @default.
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- W2599685570 date "2017-08-01" @default.
- W2599685570 modified "2023-10-15" @default.
- W2599685570 title "A novel DOBDC-functionalized MIL-100(Fe) and its enhanced CO 2 capacity and selectivity" @default.
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- W2599685570 doi "https://doi.org/10.1016/j.cej.2017.03.131" @default.
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