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- W2599692235 abstract "Abstract Tantalum pentoxide (Ta 2 O 5 ) and its solid solution phases are candidate coatings for components to be used in combustion environments. Thus, it is important to understand the response of Ta 2 O 5 to high‐temperature water vapor, a product of combustion. Thermogravimetric methods are used to examine the oxide in reactant streams of controlled water vapor contents at 1250°C‐1450°C. The observed weight loss indicates a reaction of the general form ½ Ta 2 O 5 (s) + x H 2 O(g)=TaO y ( OH ) x (g). Methodical variation in the water vapor pressure suggests the products are a mix of TaO( OH ) 3 (g) and Ta( OH ) 5 (g). Evidence of TaO( OH ) 3 (g) was observed with a sampling mass spectrometer. The measured hydroxide and oxyhyroxide vapor fluxes from Ta 2 O 5 are compared with calculated vapor fluxes from SiO 2 and Al 2 O 3 . Ta 2 O 5 exhibits fluxes similar to those from SiO 2 due to gaseous metal hydroxide formation." @default.
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- W2599692235 date "2017-03-25" @default.
- W2599692235 modified "2023-09-25" @default.
- W2599692235 title "Interactions of Ta<sub>2</sub> O<sub>5</sub> with water vapor at elevated temperatures" @default.
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- W2599692235 doi "https://doi.org/10.1111/jace.14796" @default.
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