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• W2599698452 endingPage "1244" @default.
• W2599698452 startingPage "1238" @default.
• W2599698452 abstract "Examining of the hydride transfer reaction between Cp*(Ph2PNtBuPPh2)FeH (Ph2PNtBuPPh2 = N,N-bis(diphenylphosphanyl)tert-butylamine, 1-H) and 1-benzyl-3-carbamoylpyridinium cation (BNA+) in different solvents, we found that the solvents exert considerable influence on the hydride transfer processes. A coordinating solvent molecule such as MeCN is not only a ligand which stabilizes the organo-iron fragment producing [Cp*(Ph2PNtBuPPh2)Fe(NCMe)]+ ([1(NCMe)]+), but also assists the hydride transfer. In THF, reaction of 1-H with BNA+ under high pressure of nitrogen (60 psi) giving the iron(II)–nitrogen complex [Cp*(Ph2PNtBuPPh2)Fe(N2)]+ ([1-N2]+) and BNAH. In CH2Cl2, [1-N2]+ catalyzes the conversion of 1-H to Cp*(Ph2PNtBuPPh2)FeCl (1-Cl), which hampers the expected hydride transfer reaction. In the presence of MeCN, the hydride transfer process in THF, CH2Cl2, or benzene was achieved affording the reduced BNAH and [1(NCMe)]+. New iron complexes in the [Cp*(Ph2PNtBuPPh2)FeX]n+ series (where n = 0, X = H or Cl; n = 1, X = MeCN, N2, or Cl–) were obtained and well characterized." @default.
• W2599698452 created "2017-04-07" @default.
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• W2599698452 date "2017-03-24" @default.
• W2599698452 modified "2023-10-18" @default.
• W2599698452 title "Solvent Effects on Hydride Transfer from Cp*(P-P)FeH to BNA⁺ Cation" @default.
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• W2599698452 doi "https://doi.org/10.1021/acs.organomet.6b00907" @default.
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