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• W2599809743 abstract "Two polyphosphates containing two types of polymerization of the [PO4] groups, Rb3Sr2P7O21 and Cs3Sr2P7O21, were grown through a spontaneous nucleation method. Single-crystal X-ray diffraction data were collected in order to determine their structures. Interestingly, Rb3Sr2P7O21 is the first example of two kinds of [PO3]∞ linear chains coexisting in one phosphate structure. However, in the structure of Cs3Sr2P7O21, the isolated [P4O12] ring and the 1D [PO3]∞ chain can be observed, which is also rare in phosphates. After careful structural analysis, the alkali-metal cations have an effect on the polymerization of the [PO4] groups and make Rb3Sr2P7O21 and Cs3Sr2P7O21 crystallize in different space groups. What is more, IR spectra, UV–vis–NIR diffuse reflectance spectroscopy data, and first-principles theoretical calculations were adopted to determine the optical properties and the structure–properties relationship of the compounds." @default.
• W2599809743 created "2017-04-07" @default.
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• W2599809743 date "2017-03-15" @default.
• W2599809743 modified "2023-10-16" @default.
• W2599809743 title "A₃Sr₂P₇O₂₁ (A = Rb, Cs): Two Polyphosphates Based on Different Types of P–O Chains and Ring Structures" @default.
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• W2599809743 doi "https://doi.org/10.1021/acs.inorgchem.6b03032" @default.
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