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- W2599874444 abstract "Abstract Chemical or electrochemical one‐electron oxidation of 5‐ N ‐arylaminothiazoles was found to afford stable radical cations. For chemical oxidation, 1 equivalent of [(4‐BrC 6 H 4 ) 3 N][SbCl 6 ] (Magic Blue, MB) was added to CH 2 Cl 2 solutions of the thiazoles, and the thus‐obtained radicals showed light absorption in the near‐infrared region. Electrochemical oxidation also led to bathochromic shifts in the absorption bands, and the obtained spectra were similar to those derived from the chemically oxidized species. These radicals afforded electron paramagnetic resonance (EPR) spectra that are consistent with the notion of stable nitrogen radicals (half‐life≤385 h). The EPR spectrum of a thiazole containing 4‐dimethylaminophenyl groups on the nitrogen atom at the 5‐position changed significantly upon adding >3 equivalents of MB. Details of the electronic structures of the experimentally obtained radical cations were generated from theoretical calculations." @default.
- W2599874444 created "2017-04-07" @default.
- W2599874444 creator A5034491292 @default.
- W2599874444 creator A5041284196 @default.
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- W2599874444 creator A5068666324 @default.
- W2599874444 creator A5088900279 @default.
- W2599874444 creator A5089103422 @default.
- W2599874444 creator A5089902442 @default.
- W2599874444 date "2017-03-15" @default.
- W2599874444 modified "2023-10-14" @default.
- W2599874444 title "Experimental and Theoretical Examination of the Radical Cations Obtained from the Chemical and Electrochemical Oxidation of 5-Aminothiazoles" @default.
- W2599874444 cites W1216830087 @default.
- W2599874444 cites W1554995342 @default.
- W2599874444 cites W1662491185 @default.
- W2599874444 cites W1966498756 @default.
- W2599874444 cites W1970827659 @default.
- W2599874444 cites W1973414278 @default.
- W2599874444 cites W1975707466 @default.
- W2599874444 cites W1982721060 @default.
- W2599874444 cites W1989187148 @default.
- W2599874444 cites W1989658787 @default.
- W2599874444 cites W1992354463 @default.
- W2599874444 cites W1997409988 @default.
- W2599874444 cites W2001483277 @default.
- W2599874444 cites W2002065095 @default.
- W2599874444 cites W2003653856 @default.
- W2599874444 cites W2003857863 @default.
- W2599874444 cites W2004651765 @default.
- W2599874444 cites W2010032972 @default.
- W2599874444 cites W2011258243 @default.
- W2599874444 cites W2013226985 @default.
- W2599874444 cites W2014061045 @default.
- W2599874444 cites W2015982432 @default.
- W2599874444 cites W2019155364 @default.
- W2599874444 cites W2027762558 @default.
- W2599874444 cites W2034338275 @default.
- W2599874444 cites W2041065742 @default.
- W2599874444 cites W2049286650 @default.
- W2599874444 cites W2054429097 @default.
- W2599874444 cites W2058664357 @default.
- W2599874444 cites W2060500871 @default.
- W2599874444 cites W2062852634 @default.
- W2599874444 cites W2063074480 @default.
- W2599874444 cites W2064813419 @default.
- W2599874444 cites W2065985682 @default.
- W2599874444 cites W2066287489 @default.
- W2599874444 cites W2071200300 @default.
- W2599874444 cites W2079485974 @default.
- W2599874444 cites W2086399204 @default.
- W2599874444 cites W2090028090 @default.
- W2599874444 cites W2095237012 @default.
- W2599874444 cites W2097959323 @default.
- W2599874444 cites W2099520622 @default.
- W2599874444 cites W2100463247 @default.
- W2599874444 cites W2104238415 @default.
- W2599874444 cites W2114435676 @default.
- W2599874444 cites W2125388122 @default.
- W2599874444 cites W2128711907 @default.
- W2599874444 cites W2145513890 @default.
- W2599874444 cites W2146302720 @default.
- W2599874444 cites W2147244414 @default.
- W2599874444 cites W2158803961 @default.
- W2599874444 cites W2162830594 @default.
- W2599874444 cites W2163457381 @default.
- W2599874444 cites W2170468713 @default.
- W2599874444 cites W2171526606 @default.
- W2599874444 cites W2177113984 @default.
- W2599874444 cites W2180470230 @default.
- W2599874444 cites W2192846593 @default.
- W2599874444 cites W2222040778 @default.
- W2599874444 cites W2227638303 @default.
- W2599874444 cites W2258411964 @default.
- W2599874444 cites W2269445948 @default.
- W2599874444 cites W2281131147 @default.
- W2599874444 cites W2284177472 @default.
- W2599874444 cites W2293833550 @default.
- W2599874444 cites W2296555224 @default.
- W2599874444 cites W2312256420 @default.
- W2599874444 cites W2312528056 @default.
- W2599874444 cites W2314427403 @default.
- W2599874444 cites W2323444999 @default.
- W2599874444 cites W2324960642 @default.
- W2599874444 cites W2325954635 @default.
- W2599874444 cites W2326864027 @default.
- W2599874444 cites W2334442916 @default.
- W2599874444 cites W2343700314 @default.
- W2599874444 cites W2403221377 @default.
- W2599874444 cites W2406704521 @default.
- W2599874444 cites W2407008495 @default.
- W2599874444 cites W2413138209 @default.
- W2599874444 cites W2467932513 @default.
- W2599874444 cites W2472922323 @default.
- W2599874444 cites W2491458126 @default.
- W2599874444 cites W2492878007 @default.
- W2599874444 cites W2507187899 @default.
- W2599874444 cites W2507353797 @default.
- W2599874444 cites W2511341088 @default.