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• W2600317898 abstract "Two new vicinal dioxime ligands containing thiosemicarbazone units (L 1 H 2 and L 2 H 2 ) were synthesized and characterized using 1 H NMR, 13 C NMR, heteronuclear multiple quantum correlation, mass, infrared and UV–visible spectroscopies, elemental analysis and magnetic susceptibility measurements. In addition, homotrinuclear nickel(II), copper(II) and cobalt(II) complexes with a metal‐to‐ligand ratio of 3:2 for L 1 H 2 and L 2 H 2 were prepared. Synthesis of nickel(II) complex containing a BF 2 + bridge was carried out using a precursor hydrogen‐bridged nickel(II) complex via the template effect. All metal–ligand complexes were tested against two human cancer cell lines (HL‐60 and HT‐29) for their antiproliferative and apoptotic activities. The results showed that [Co(L 2 H) 2 (H 2 O) 2 ] and [Ni(L 2 H) 2 ] exhibited the strongest antiproliferative activity with I p C 50 values ranging between 5 and 10 μM, while [Co(L 2 H) 2 (H 2 O) 2 ] and [Ni(L 2 H) 2 ] both induced necrosis of HT‐29 cells and 60 and 65% apoptosis in HL‐60 cells, respectively." @default.
• W2600317898 created "2017-04-07" @default.
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• W2600317898 date "2017-03-27" @default.
• W2600317898 modified "2023-10-18" @default.
• W2600317898 title "Synthesis and use of dioxime ligands for treatment of leukemia and colon cancer cells" @default.
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• W2600317898 doi "https://doi.org/10.1002/aoc.3752" @default.
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