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- W2600357267 abstract "Cis-enediyne-type compounds have received much attention as potent antitumor antibiotics. The conventional synthesis of cis-enediynes in solution typically involves multiple steps and various side reactions. For the first time, selective one-step synthesis of cis-enediyne from a single reactant is reported on a Ag(111) surface with a yield up to 90 %. High selectivity for the formation of cis-enediyne originates from the steric effect posed by weak intermolecular interactions, which protect the cis-enediyne from further reaction. A series of comparative experiments and DFT-based transition-state calculations support the findings. The described synthetic approach for directing reaction pathways on-surface may illuminate potential syntheses of other unstable organic compounds." @default.
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- W2600357267 date "2017-03-27" @default.
- W2600357267 modified "2023-10-12" @default.
- W2600357267 title "Highly Selective Synthesis of cis -Enediynes on a Ag(111) Surface" @default.
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- W2600357267 doi "https://doi.org/10.1002/anie.201701142" @default.
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