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• W2600422079 endingPage "3857" @default.
• W2600422079 startingPage "3852" @default.
• W2600422079 abstract "Unprecedented palladium-catalyzed denitrogenative Suzuki and carbonylative Suzuki coupling reactions of benzotriazoles with boronic acids have been realized, which afforded structurally diverse ortho-amino-substituted biaryl and biaryl ketone derivatives. The key to this success is due to the development of a rationally designed strategy to achieve the ring opening of benzotriazoles with a synergistic activating-stabilizing effect, which enables the in situ generation of the corresponding ortho-amino-arenediazonium species. The present work opens up a new avenue to utilize benzotriazoles as synthetic equivalents of ortho-amino-arenediazoniums, which otherwise could not be directly accessed by existing synthetic methods." @default.
• W2600422079 created "2017-04-07" @default.
• W2600422079 creator A5020186215 @default.
• W2600422079 creator A5042463133 @default.
• W2600422079 creator A5051167196 @default.
• W2600422079 creator A5077802694 @default.
• W2600422079 date "2017-01-01" @default.
• W2600422079 modified "2023-10-15" @default.
• W2600422079 title "Denitrogenative Suzuki and carbonylative Suzuki coupling reactions of benzotriazoles with boronic acids" @default.
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• W2600422079 doi "https://doi.org/10.1039/c7sc00367f" @default.
• W2600422079 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5578364" @default.
• W2600422079 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28966777" @default.
• W2600422079 hasPublicationYear "2017" @default.
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• W2600422079 hasAuthorship W2600422079A5020186215 @default.
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