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• W2600440938 endingPage "2652" @default.
• W2600440938 startingPage "2643" @default.
• W2600440938 abstract "Two new closo ‐carborane selenolated ligands, 2‐[(1′‐Me‐1′,2′‐ closo ‐C 2 B 10 H 10 )SeCH 2 ]C 5 H 4 N ( L 1 ) and 2,6‐[(1′‐Me‐1′,2′‐ closo ‐C 2 B 10 H 10 )SeCH 2 ] 2 C 5 H 3 N ( L 2 ), were prepared by the C–H activation of 1‐Me‐1,2‐C 2 B 10 H 11 with n BuLi, followed by the insertion of elemental selenium into the C–Li bond and reaction with 2‐(BrCH 2 )C 5 H 4 N or 2,6‐(BrCH 2 ) 2 C 5 H 3 N, respectively. The closo species L 1 and L 2 were deboronated with CsF to give the nido ‐carborane cesium salts Cs[2‐{(1′‐Me‐1′,2′‐ nido ‐C 2 B 9 H 9 )SeCH 2 }C 5 H 4 N] ( 1 ) and Cs 2 [2,6‐{(1′‐Me‐1′,2′‐ nido ‐C 2 B 9 H 9 )SeCH 2 } 2 C 5 H 3 N] ( 2 ). The isolation of the complexes [Ag(OTf)( L 2 )] ( 3 , OTf = triflate), [Ag(PPh 3 )( L 2 )][OTf] ( 4 ), [Cu( L 2 )(MeCN)][PF 6 ] ( 5 ), and [Cu( L 2 ) 2 ][PF 6 ] ( 6 ) indicates the coordination ability of L 2 towards these metals. The molecular structures of L 1 and L 2 were established by single‐crystal X‐ray diffraction. Quantum‐chemical calculations confirmed the molecular geometries and also the presence of C–H ··· Se intramolecular interactions as well as C–H ··· H–B and B–H ··· π intermolecular interactions." @default.
• W2600440938 created "2017-04-07" @default.
• W2600440938 creator A5011775839 @default.
• W2600440938 creator A5020255703 @default.
• W2600440938 creator A5041509482 @default.
• W2600440938 creator A5061721957 @default.
• W2600440938 creator A5063453234 @default.
• W2600440938 creator A5068099743 @default.
• W2600440938 creator A5084842559 @default.
• W2600440938 date "2017-05-26" @default.
• W2600440938 modified "2023-10-16" @default.
• W2600440938 title "(N,Se) and (Se,N,Se) Ligands Based on Carborane and Pyridine Fragments – Reactivity of 2,6‐[(1′‐Me‐1′,2′‐ <i>closo</i> ‐C ₂ B ₁₀ H ₁₀ )SeCH ₂ ] ₂ C ₅ H ₃ N towards Copper and Silver" @default.
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