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- W2600602603 abstract "A mild and transition-metal-free synthesis of β-keto arylthioethers has been developed by the aryne triggered [2,3] Stevens rearrangement of allylthioethers. The key sulfur ylide intermediate for the rearrangement was formed by the S-arylation of allylthioethers with arynes generated from 2-(trimethylsilyl)aryl triflates using CsF. Later, the reaction products are converted into valuable heterocycles in two steps." @default.
- W2600602603 created "2017-04-07" @default.
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- W2600602603 date "2017-04-03" @default.
- W2600602603 modified "2023-10-15" @default.
- W2600602603 title "Synthesis of Functionalized β-Keto Arylthioethers by the Aryne Induced [2,3] Stevens Rearrangement of Allylthioethers" @default.
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- W2600602603 doi "https://doi.org/10.1021/acs.joc.7b00479" @default.
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