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- W2600702552 abstract "A new route to phosphines was developed by a method that features a pre-join and transform process that proceeds via acylphosphine intermediates that may be readily prepared from carboxylic acids and disubstituted phosphines. The efficient decarbonylations of these acylphosphines using a nickel catalyst delivered the corresponding phosphines. This method shows that the carboxyl group can play a role similar to halides or triflates for introducing a substituted phosphorus atom on an aromatic ring." @default.
- W2600702552 created "2017-04-07" @default.
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- W2600702552 date "2017-03-30" @default.
- W2600702552 modified "2023-10-18" @default.
- W2600702552 title "Differentially Substituted Phosphines via Decarbonylation of Acylphosphines" @default.
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- W2600702552 doi "https://doi.org/10.1021/acs.orglett.7b00579" @default.
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