Matches in SemOpenAlex for { <https://semopenalex.org/work/W2600708410> ?p ?o ?g. }
- W2600708410 endingPage "159" @default.
- W2600708410 startingPage "150" @default.
- W2600708410 abstract "The thermal decomposition of Mo(VI) acetylacetonate salt (Mo Acac) has been performed under helium stream between room temperature and 700 °C (2 K min−1) and monitored by thermogravimetric analysis coupled to mass spectrometry. The viscous MoO2(C5H7O2)2 salt evolves two acetylacetonato ligands between room temperature and 325 °C which decompose into methane and acetic acid. Molybdenum dioxide MoO2(s) is the final product of decomposition as confirmed by the thermal behavior of pure MoO3(s) salt and thermodynamic calculations. In the presence of NH4+–ZSM-5 zeolite (6 wt.% of Mo), the departure of the two ligands was accelerated and the salt transformed into MoO2(s) at 285 °C. However, the oxidation of CH4 by molecular oxygen was inhibited at 245 °C by the simultaneous formation of MoO3(s) and MoO2(OH)2(g). The solid–state exchange of the volatile MoO2(OH)2 specie and the protonated zeolite occurs between 320 and 570 °C. Nevertheless, the exchange process overlaps with the partial dehydroxylation of the zeolite at 520 °C." @default.
- W2600708410 created "2017-04-07" @default.
- W2600708410 creator A5005035714 @default.
- W2600708410 creator A5010491159 @default.
- W2600708410 creator A5012845287 @default.
- W2600708410 creator A5039920152 @default.
- W2600708410 creator A5055941303 @default.
- W2600708410 creator A5057502545 @default.
- W2600708410 creator A5062058589 @default.
- W2600708410 date "2017-06-01" @default.
- W2600708410 modified "2023-09-25" @default.
- W2600708410 title "Solid–state ion exchange of molybdenum ( VI ) acetylacetonate into ZSM-5 zeolite" @default.
- W2600708410 cites W1437608481 @default.
- W2600708410 cites W1965765976 @default.
- W2600708410 cites W1971566490 @default.
- W2600708410 cites W1978262073 @default.
- W2600708410 cites W1986464624 @default.
- W2600708410 cites W1991427594 @default.
- W2600708410 cites W1991739965 @default.
- W2600708410 cites W1993333109 @default.
- W2600708410 cites W2004057365 @default.
- W2600708410 cites W2004597439 @default.
- W2600708410 cites W2010993734 @default.
- W2600708410 cites W2011308252 @default.
- W2600708410 cites W2011631987 @default.
- W2600708410 cites W2012306640 @default.
- W2600708410 cites W2013207612 @default.
- W2600708410 cites W2014323327 @default.
- W2600708410 cites W2022388302 @default.
- W2600708410 cites W2025544322 @default.
- W2600708410 cites W2026159816 @default.
- W2600708410 cites W2033988363 @default.
- W2600708410 cites W2035834594 @default.
- W2600708410 cites W2040158737 @default.
- W2600708410 cites W2055344272 @default.
- W2600708410 cites W2055380046 @default.
- W2600708410 cites W2067843071 @default.
- W2600708410 cites W2109052989 @default.
- W2600708410 cites W2111207911 @default.
- W2600708410 cites W2132539397 @default.
- W2600708410 cites W2136771286 @default.
- W2600708410 cites W2142242175 @default.
- W2600708410 cites W2170540086 @default.
- W2600708410 cites W2171866093 @default.
- W2600708410 cites W2256993472 @default.
- W2600708410 cites W2299336055 @default.
- W2600708410 cites W2316534872 @default.
- W2600708410 cites W2316858789 @default.
- W2600708410 cites W2322354531 @default.
- W2600708410 cites W2325572296 @default.
- W2600708410 cites W2474074448 @default.
- W2600708410 cites W2502140224 @default.
- W2600708410 cites W2566959879 @default.
- W2600708410 cites W2983223806 @default.
- W2600708410 doi "https://doi.org/10.1016/j.tca.2017.03.020" @default.
- W2600708410 hasPublicationYear "2017" @default.
- W2600708410 type Work @default.
- W2600708410 sameAs 2600708410 @default.
- W2600708410 citedByCount "8" @default.
- W2600708410 countsByYear W26007084102017 @default.
- W2600708410 countsByYear W26007084102018 @default.
- W2600708410 countsByYear W26007084102019 @default.
- W2600708410 countsByYear W26007084102020 @default.
- W2600708410 countsByYear W26007084102021 @default.
- W2600708410 countsByYear W26007084102022 @default.
- W2600708410 countsByYear W26007084102023 @default.
- W2600708410 crossrefType "journal-article" @default.
- W2600708410 hasAuthorship W2600708410A5005035714 @default.
- W2600708410 hasAuthorship W2600708410A5010491159 @default.
- W2600708410 hasAuthorship W2600708410A5012845287 @default.
- W2600708410 hasAuthorship W2600708410A5039920152 @default.
- W2600708410 hasAuthorship W2600708410A5055941303 @default.
- W2600708410 hasAuthorship W2600708410A5057502545 @default.
- W2600708410 hasAuthorship W2600708410A5062058589 @default.
- W2600708410 hasConcept C117760992 @default.
- W2600708410 hasConcept C124681953 @default.
- W2600708410 hasConcept C145148216 @default.
- W2600708410 hasConcept C147789679 @default.
- W2600708410 hasConcept C160434732 @default.
- W2600708410 hasConcept C161790260 @default.
- W2600708410 hasConcept C178790620 @default.
- W2600708410 hasConcept C179104552 @default.
- W2600708410 hasConcept C185592680 @default.
- W2600708410 hasConcept C2776371256 @default.
- W2600708410 hasConcept C2776673659 @default.
- W2600708410 hasConcept C2778077586 @default.
- W2600708410 hasConcept C516920438 @default.
- W2600708410 hasConcept C549387045 @default.
- W2600708410 hasConcept C60100273 @default.
- W2600708410 hasConceptScore W2600708410C117760992 @default.
- W2600708410 hasConceptScore W2600708410C124681953 @default.
- W2600708410 hasConceptScore W2600708410C145148216 @default.
- W2600708410 hasConceptScore W2600708410C147789679 @default.
- W2600708410 hasConceptScore W2600708410C160434732 @default.
- W2600708410 hasConceptScore W2600708410C161790260 @default.
- W2600708410 hasConceptScore W2600708410C178790620 @default.
- W2600708410 hasConceptScore W2600708410C179104552 @default.
- W2600708410 hasConceptScore W2600708410C185592680 @default.